Hazardous Material Handling Essay Example for Free

Hazardous Material Handling EssayChemicals atomic number 18 gear up in all places they are used to enhance crop production, distill drinking water, and simplify everyday chores. But chemicals displace also be uncivilised to the environment as well as to humans if released or used inappropriately. These hazards can say place during disposal, use, transportation, storage, or production. If a chemical is released in nocent amounts or used unsafely, it can movement lifelong health effects, serious injury, death, and damage to homes, buildings, and other property.In the recent years, the Federal Bureau of Investigation in public announced that terrorists are particularly interested in releasing hazardous material as well as in targeting their containers on American soil. Alarmingly, if terrorists postdate in such an attack in a populated vicinity, the result would be devastating. The number of casualties ensuing from such an attack would be enormous dwarfing the human death count in the 911 attacks.Chemical, Biological and Nuclear Agents and IncidentsDeadly chemical, biological, and nuclear agents that may be employed by non-state actors or adversarial nations against civilians could cause mass casualties. Other than figure terrorist attacks and deliberate employment of NBC weapons during military operations, the hazards could result from the release of harmful radioactive matters, biological agents of operational significance, and industrial chemicals (Mauroni, 2007, p. 290). Basically, chemical incidents are depicted by fast onset, from minutes to hours, of apparent health indicators. While in cases of radiological and biological incidents, the onset symptoms entails days to weeks, normally with no distinctive indicators.A recent simulation by the U.S. Naval Research Laboratory revealed that if an attack should occur during a political event or other public celebrations, people could die at a rate of more than 100 per second and, within 30 minute s, up to 100,000 people could die (District of Columbia, social occasion of the Attorney General, 2005, p. 2). Likewise, a 2004 study by the Homeland Security Council found that even under less crowded circumstances, an attack in a metropolitan area would cause 100,000 hospitalizations, 10,000 severe injuries and 17,500 deaths (District of Columbia, Office of the Attorney General, 2005, p. 2).I. Chemical AgentsSeveral types of toxic cyanide compounds may be used in terrorist attacks. Potassium or sodium cyanides are pale yellow-to-white salts that can be easily utilized to poison drinks or food. When combined with chemicals that enhance skin penetration, cyanide salts can be dispersed as a intimacy poison.Toxic industrial chemicals such as mustard or nerve agents, in contrast, can be utilized in larger amounts to compensate for their wanting(p) toxicity. Initial skin contact results in slight skin irritation, which turns into more acute yellow fluid-filled lesions (U.S. Departmen t of Homeland Security, 2003). Inhalation of mustard causes breathing problems, insurance the lungs, and death by suffocation caused by water in the lungs.II. Biological AgentsBacillus anthracis, the bacterium that generates anthrax, is an attractive biological agent for terrorist attacks because it can endure diametric environmental conditions, and its inhalation could normally result in death. Anthrax can be used to contaminate water or food or disseminated in an aerosol to respectively cause ingestional or inhalational anthrax (U.S. Department of Homeland Security, 2003).III. Radiological and Nuclear Agents and DevicesAn RDD or radiological dispersal device is designed to cause contamination of radioactive material due to its diffusing function. A range of radioactive materials could be employed in a RDD, including Cobalt-60, Strontium-90, and Cesium-137 (U.S. Department of Homeland Security, 2003). wont of an RDD by terrorists could result in economic, environmental and healt h effects, as well as social and political effects. In a nuclear terrorist event, the hazards are nuclear radiation, shock or blast effect, and thermal radiation.Developments on MAZMAT Incidents ApproachesProper sample gathering is significant to preserve sample veracity for laboratory testing, to guarantee chain-of-custody backup for possible legal actions, and basically to protect those on-site responders and victims (Association of Public Health Laboratories, 2008). Accordingly, in the recent years the laboratory training programs slowly and seriously take in a proactive sample collection seminar, along with familiarization with laboratory testing methods, as well as proficiency testing program.These programs are think to assure that first responders in the field will be able to accurately use hand-held testing devices, correctly understand test results and resurrect proper action plan derived from the findings. Moreover, in view of the fact the ability to detect impending ter rorism agents is essential to effective and safe emergency response, Hazmat responders are now being trained on how to operate a range of Hazmat detection devices. As the war against terrorism has intensified, the number of technological advances and knowledge in the field of terrorist agent detection has also been improved among Hazmat teams.ConclusionHazardous materials incidents cover a diversity of possible situations including explosions, transportation accidents, spills, fires, and similar events. Hazards may acknowledge chemical reactions, health hazards, toxicity, explosives, radiological hazards, or a combination of any of the said hazards. In view of these, terrorists have a wide range of alternatives of toxic materials and means for attacks. To adequately and safely counteract Hazmat terrorist attacks, Hazmat teams are regularly modernizing, as well as participating in related trainings, as these trainings identify their strengths and weaknesses non only of their respec tive teams, but how the teams works together when disaster does arise.

Mark Twain - Racism †Huckleberry Finn Essay Example for Free

Mark bracing Racism Huckleberry Finn EssayMark straddle depicts an apprehension to racisms through the character Huckleberry Finn. He is a lily-white young boy who comes in contact with the conditions of slavery at a relatively early age. The author allows him to feel uncomfortable with the very process by which humans are classified in civil society. This view is based on how Twain created the institution of slavery to be established at the time. Twain in emphasizing his views allow his character to be confronted by situations which would force him to think about slavery and the face of racism. The young man is pressured by his experience fathers harsh racist belief as depicted in the election scene, It was lection day, and I was just about to go and vote myself if I warnt too drunk to get there but when they told me there was a State in this Country where theyd let a nigger vote, I drawed out. (Echeat, 2010)Twain creates the paradox between father and son to highlight wh ere he stood on racism. Mark Twain-Racism-Tom Sawyer Surprisely, even though Mark Twains Adventures of Tom Sawyer includes a character named Huckleberry Finn as is represented in The Adventures of HucleburyFinn the role designation is entirely different.Huckleberry Finn plays a supportive role in allowing Tom to complete his mischiefs. The author displayed very little interest of projecting a race issues his that society. Its only emergence was flashed as a minor phylogenesis in the story was in the killing of Dr Robinson by a Native American, However, there were no direct racial insinuations in the account, In the scuffle, Injun Joe stabs Dr. Robinson with muck abouts knife.. Native-American half-breed Injun Joe. (Sparknotes, 2010)To conclude It can be presumed that the time when Huckleberry Finn was written racism was Mark Twains major sociological concern. On the other hand with Tom Sawyer he was viewing morals from the perspective of parental authority and how social groups i nteract. REFERENCE Racism in Huckleberry finn. www. echeat. com. N. p. , n. d. Web. 29 May 2010. http//www. echeat. com/essay. php? t=33441. The Adventures of Tom Sawyer. www. sparknotes. com. N. p. , n. d. Web. 29 May 2010. http//www. sparknotes. com/lit/tomsawyer/summary. html.

Family communication | The Glass Castle

Family communication The Glass CastleIn The Glass Castle Jeanette tells us about the story of her life as she had have it offd it. She and her siblings had feeld a life that she describes as having a lot of stressors. Her story has memoir in which she proves to the reader that living with bad p arnts and poverty do not really determine that the kids will pinch a miserable future just as their parents. In this book, Walls reveals her life as difficult during her bringing up save yet love existed inwardly the family. In this paper, we are therefore going to look at those stressors that the family went throughJeanette sees her gravel coming out of a dumpster with some lagged clothes tied roughly her neck. Her mformer(a) lucks a family unit to live in and this lives her with no choice moreover to look for any show up that she toilet lay her head and likewise find something that can fill her stomach. It is very(prenominal) sad for Jeanette to see her mother this way as it w ould feel for anyone to watch their mothers go through this type of embarrassments. spinal column in her childhood life, Jeanette suffers some serious burns as she boils hotdogs and her dress catches fire from the stove she is using. This lives her to spend many days in a topical anaesthetic hospital near her home area in Arizona. Her parents prove to be so unconditional as they dont lift out as much care as it would be imagined even by the hospital staff. The rumor goes throughout the hospital scarce Jeanette does not discuss this issue with the parents.Her father takes the risk of grabbing and sneaking his niggling daughter out of the hospital escaping all the bills that he was intended to pay for the hospital to release the daughter. This happens even before she heals completely. The escape lives the family with no choice but running away from their hometown for they would highly deal with the low. They have to travel long distance and through hot deserts. They later(preno minal) settle in several towns in which the father is unable to pay kinsfolk rent and this makes them keep on vacating.The father becomes a drunkard and cannot back up onto his job despite his intelligence and giving on mechanical background. This makes the families life a living hell full of poverty and problems that never come to an end. His promise to his children to build a good house for the family fails as he cannot raise the amount to put up such a house. The fathers behavior and failure lives the children helpless and end up begging their mother to work and bring food to the table.Luckily, the mother holds a degree in teaching but cannot get herself a job for she is lazy and the children have to blow up her out of bed. This behavior has severally made her loose her job despite the fact that her residential area lucks qualified teachers. She later secures a job but her salary does not fully help the family. The father demands for her paycheck and spends the money on his drink and his own benefits.This miserable state keeps on taking place for a long time living the children to go on sleeping on uncomfortable hard boxes and watching their parents fight in daily bases. The childrens bellies grumble every time due to hanger. They feed on anything that would fill their bellies and not for the sake of having a balanced diet meal like in other families. For this case, the mother has to teach them how to take rotten food down their throat while they hold the noses.The family went through these stressors and it affects their relationship since the kids see the father as irresponsible and harsh as they fear him. It also affects the husband-wife relationship since the mother has to fight her husband daily. The communication is on its negative side for the mother does not hold any ability to fight for her right to manage the salary she earns. The children also suffer silently as they have to spend their nights on hard boxes but cannot communicate to the fath er and express their grievances.Despite all poverty and stressors that they experience, the family has a genuine and strong love towards each other. They remain loyal and the familys father Rex is very encouraging, tender and wise when handling his children and wife whenever he is sober. As Jeanette retroverts the reader her memoir, she explains her life so well to ensure that she gives the real story that has experienced in her growing up.Jeanette and her siblings grow in the worst conditions that no one can ever deserve or think of but it does not change their feelings towards their parents. They cover loving them without realizing how cruel they have been until when they grow up and mature (Jeannette, p134). Jeanette spends her teenage life in the west side of Virginia where the father is squeeze to retreat to their home area after experiencing a miserable life in Arizona.Here, the life of this family does not get better but continues to hit its worst points as they live under a roof that leaks. Rex tries to mend the roof but it does not do them any good either. In fact, they also have to face challenges as they have nowhere to dispose their rubbish and waste. The family is forced to put up with a smelly condition as they dispose the wastes in small holes that they tire.solid food also continues to be another problem for they cannot afford to buy any and they almost go without it. Jean is forced to go to high inform and dig leftovers from the garbage as her father continues to drink irresponsibly as usual. As their lives get worse and miserable, Jeanettes mother ends up doing the most awful things one can ever imagine. Jeanette and her siblings find a ring made of diamond and decide to sell it so that they could buy food. The mother does not agree with this idea since she wants to proceed her dignity. This action lives the family in the some state of lacking food and starving.When Jeanette or her siblings go out playing with other kids, they are mocke d and addressed as kids who are health epidemic for they live in garbage places. Her family and their neighbors always fight for they keep on picking on their perverted situation. Hours spent in school are also not favoring to her either she has to steal other kids food or hide in the bathroom at lunch hours while the others take their food. After lunch, she comes out and collects the leftovers and eats them for she has no choice over it.She later gets tired of this life and decides to go to New York where she gets further studies. She lives her family with the aim of getting cognition that will secure her a good job and enable her to take care of her family. While she is in New York, her father gets ill and is admitted to the hospital wo(e) from Tuberculosis. She visits him and pleads with him not to leave the hospital before he fully recovers.Later, she receives a call from her parents that they were homeless and had no place to go. She decides to move in with them for she still has not bad(p) love for them despite the life they had offered in during her child life (Jeannette, p100). People around Jeanette discourage her about this idea saying that it was not good to give the homeless a place to stay for it makes them lazy and reluctant on finding their own home his pisses her off but she does not show it to them.Jeanette is forced to change the idea of attending a private school while her parents have no home. Instead, she opts to stay and take care of them but her brothers go against her close telling her that her mother owned a whole lot of jewelry she could sell and that she has a land in Texas where her husband and her could go and live. Her husband behavior does not change and she is forced to live him. She has although kept a secret land away from her family and when Jeanette discovers this she is really annoyed with her.After her brothers death, Mary then goes to live in his land her in which her life does not change. She continues living miserabl y especially now that her communication with her children and husband had been disturbed. It is true to say that the love of the daughter towards the mother by now has changed unlike before when she was still a young girl and innocent to place judgment on her parents treatment towards them.Jeanette later marries Eric whom she has dated for five years. She moves in with him to a better house since Eric came from a rich family. She tries her best to take care of her younger sister who tends to take the unlawful direction in her life. Jeanettes life has changed and she feels that her siblings should follow her steps for they have faced the same miserable lives.Her mother cannot hold on the problems she is facing and goes ahead to bear money from Jeanettes husband a step that annoys her to a great extent. What annoys her most is the fact that she has kept the land that she owns away from the family despite all the poverty and problems that they went through during their earlier life. As if this is not enough, she goes ahead to borrow money from Jeanettes new husband so that she could purchase the other half of the land.Later, Jeanette visits her father who tells her that she is suffering from a disease that he contracted while fighting with a Nigerian who happened to be a drug dealer. He later suffers from a hurt withdraw and is placed in a machine that supports his life. He spends his last moments with Jeanette who holds his arm recalling of how he had told them that he would prefer his body placed on a mint when he dies- he later dies after an hour and the machine turned off. Jeanette grieves her fathers death and in one year, she lives her husband as she saw him as not the right man for her.Work citedJeannette Walls. The Glass Castle A Memoir. Scribner, 2006 45-250

Malaysias Tourism Industry: An Analysis

Malaysias Tourism Industry An Analysis1.0 IntroductionThe Malaysian duty touring carry constancy seems to represent an increasingly important vault of heaven and it palys a major business office in spite of appearance the Malaysian economy and has been responsible for the growth of the economy all over the years. This industry has become a real important source of revenue for the overall economic development of the province. For an industry that is in truth important, it is empirical that the government send wordvas steps to make tourism a strategic economic and art priority. Logistics is a practice that has been employ in several other industries but right a style is appearing to be very helpful and applic fitted in the tourist and recreation sector. It is observed here that the travel and tourism industry in Malaysia has go along to break over the years and this occurrence industry has managed to make a significant contribution to Malaysias revenue. What is known here is that the Malaysian travel and tourism industry does concern to remain to be peerless of the main income earners that continue to help to strengthen Malaysias balance of payment. The tourism industry of Malaysia is equal to(p) of universe classified into slightly seven categories ande these be as followsEdu-tourismDomestic tourismShopping tourismMedic-toursmEco-tourismAgro-TourismSports tourismIn this inquiry, there pull up stakes be an examination of the issues and problems relating to the logistics practices by firms in various relevant industries that argon related to the Malaysain tourism industry and the way that these firms carry out their logistics practices. In essence, the main focus would be on contrive essential strategies that would en up to(p) these firms to be able to enahnce their practices relating to logistics for the put on of all of the industry. in that location argon a descend of strategies that can be adopted by these firms in assemble to e nhance their movement in this enquiry result be concentrated on identifying one strategy that can help the firms in the tourist industry in Malaysia to enhance their logistics practices. In particular, the viability of the logistics make up analysis strategy will be examined here and a theorization will be make about the viability of the utilization of this strategy to enhance the performance of firms in the tourism industry in Malaysia and the performance of the industry itself.This explore will be dependent of producing efficient outputs that will make it possible for conclusions to be drawn about the logistics efficacy of the firms operating within the tourism industry in Malaysia and the possible slipway to increase the efficiency of a firms logistics operations in order to ensure enhanced and efficient performance within the industry. After all relevant dedicate has been factored in, the enquiryer will be able to highlight all the logistic factors affecting travel and tourism industry in Malaysia and would be able to survive at a conclusion that can then be used to devise a strategy or framework that can be used by firms in the industry to perfect their logistics practices.1.1 Problem StatementAs famed, there argon a fargon of factors that slang been identified as existence factors that have caused for the tourism industry to experience setbacks and it is these kinds of setbacks thatt have the impact of reducing the performance of the firms within this industry. Logistical factors atomic number 18 the kinds of factors that could determine the efficiency at which the an nerve within the indsutry is able to operate at maximum efficiency. For a very profitable industry equivalent the Malaysian tourism industry, it is very essential for each kind of factor within the industry that might cause for issues to be faced by the Malaysian tourism sector to be identified and addressed, in order to ensure that this industry continues to be a able t o bring in revenue for Malaysia. Problems relating to logistics can always be an impediment to the progress of a firm and even an industry, if all the firms do not have an efficient logistics strategy. Among the relevant firms that are impacted by logistics in this industry include firms from the works, hospitality, tour operating, tourism oriented and recreation oriented firms. in all of these firms are able to utlize various logistics strategies in order to reduce be and improve their run. These firms are paltry from logistics management issues that are in turn reducing the performance of the entire industry and hence it is essential that these firms adopt a strategy that would improve logistics practices.1.2 substance of the ResearchThis research is signficant because it addresses a very essential issue relating to logistics and the way that the logistical practices of an organisation within the tourism industry can affect the way that the firm performs. This research will determine the state of the logistical practices of firms in the industry and the output will be used to determine if there is a deficiency in the logistics practices of firms in the industry. The research will then attempt to make a proposal of strategies in order to perfect the logistics practices of firms in the organisation through the use of strategies and frameworks.1.3 Scope of ResearchThis research will be focused primarily on examining the logistics practices of firms in the Malaysian tourism industry and the efficiency at which they carry out their logistics practices. The scope would be on examining the logistics practices of firms only from the tourism industry in Malaysia and to propose a strategy within the empyrean of logistics that is capable of solving these inefficiencies and issues faced by these firms.1.4 Research ObjectivesThe main research objectives of the project will be outlined here. The main objective here will be to determine the logistic factors affectin g travel and tourism industry in Malaysia. So as to be able. To be able to achieve the native objective of this research paper, there are a few secondary objectives that have to be determined, among them are as followsExamining the logistics performance of the tourism industry in MalaysiaDetermining if Malaysia firms in the tourism industry are suffering from a deficiency in logistcal performanceExamining the strategies that can be adopted in order for logistics performance of to be capable of existence enhanced in firms operating within the tourism industry, in order to enhance the overall performance of the Malaysian tourism industry.1.5 Research QuestionsWhat is the level of logistics performance of the tourism industry in Malaysia?Is firms in the Malaysian tourism industry suffering from a deficiency in logistcal performance?What are the strategies that can be adopted in order for logistics performance to be capable of being enhanced in firms operating within the tourism indus try so as to enhance the overall performance of the Malaysian tourism industry?2.0 Literature ReviewIn this chapter, there will be a literature review that will be carried out on this research topic and hence this means that there will be a review of literature relating tourism and logistical infrastructure. The review commences with an review of literature that relates to the description of the tourism product, the benefits of investing in tourism, a review of literature concerning tourism management, the charactertistics of the tourism industry, the opinions of past researchers about the strategies that can be used to enahnce the logistics practices within the industry to deliver value, the value chain of the tourism industry.2.1 Characteristics of the Tourism Industyharmonize toDwyer and Forsyth, (1997),the tourism industry does have a number of attributes of a competitive market. Essentially, there are very few barriers to entry into the market, the market can be expound as b eing a truly global market that have a few unnatural barriers to trade, there are a adult number of firms within the industry and the worths are set on the sole basis of market expectations, essentially.Within a highly competitive market deal tourism, there does not seem to be any difference, when it comes to the yield from diametrical types of tourists. Within this kind of a competitive market, resources have to be deployed at a level that does reflect their opportunity cost. What this mean here is that they will be employed at a level that makes it possible to provides a sufficient return to investors when talking in terms of the cost of capital. If there are resources which provide above normal profits they are bid up in price and any abnormal profit is dissipated into the cost of capital(Dwyer and Forsyth, 1997).2.2 The Tourism Product Described2.2.1 Features of the Tourism ProductIt has been stated thatYilmaz and Bititci, (2006),that the tourism product is verbalize to car ry the characteristics pertaining to the service product as well as the characteristics that are special to the tourism industry, and it is this that tends to make the tourism product to be more different from physical goods. What can be tell here is that these characteristics are very efficient when it relates to the performance of the tourism establishments and they have to be taken into consideration when performance measurement and management systems are being designed. A very special and distinctive features of the tourism product can eb utter as it being otiose to be seen and touched physically before being purchased, and which means that it is intangible. It is appreicated here that this kind of intangibility does essentially make it harder to buy but easier to be able to distribute(Evans et al., 2003).It does overly make tourism to be dependent on the representations as well as the descriptions that are within printed or audio-visual forms, and, hence, it is theorized here that training is the vital tool which makes it possible to bind producers within the travel industry(Ujma, 2001).The main role of travel teaching that is for consumers can be siad to be very significant as visitors tend become exposed to trhe risk in buying vacations that they believe to be able to satisfy their various involve and wants that are give tongue to to be very important to them(Mill and Morrison, 2002) and (Yilmaz and Bititci, 2006).The next feature of the tourism product is its perishability and what can be stated here is that the tourism product, like an aeroplane seat or hotel bed, is incapable of being stored for future sale. This can be decribed as being a differences that is present between tourism and manufacturing products. It is this kind of characteristic of the tourism product that does haev an impact on the marketing efforts as well as the operations of the tourism businesses. The main marketing challenge here would be to operate at full capacity fo r as long as possible and the company would have to design various kinds of marketing strategies for the ultimate conclude of stimulating the demand(Callaghan et al., 1994) and (Yilmaz and Bititci, 2006).2.2.2 The Value Chain of the Tourism IndustryThis industry is one that has been analysed in a holistic manner through a number of statistical distribution channel perspective by a number of authors and researchers(Middleton and Clark, 2001), (Mill and Morrison, 2002), (Halloway, 1998) and (Laws, 1997).A common theme that has been noted among a number of researchers is that there seems to be a lack of customer-oriented approach within the end-to-end value chain. It is noted that customers tend to view the tourism product as something that is a seamless product and that considers to be handled from the view point of the customer in order to be able to measure the tourism value chain in an efficient way. There has been a great amount of emphasis that has been given to service, pers ona, and customer satisfaction issues, and within the connection to the business performance within the tourism industry, it is quite surprise not to find a customer-oriented approach present within the tourism value chain(Yilmaz and Bititci, 2006).The tourism value chain is noted to commence with the customer order and more often than not, customers or tourists do have a few alternatives when it comes to purchasing the tourism product and it is noted here that they are capable of either arranging their travel plan with the assistence of tour operators or even outbound travel agents, which does have an advantage of taking professional advice in simile to all of the holiday package without any kind of thinking or arranging it themselves and this permits them to be very flexible when it comes to their travel experience. It can be said here that incoming travel agents is capable of being used to make transfer arrangements from/to the airport to/from the hotel and for daily excursions as well as other activities that are normally held at the destination(Yilmaz and Bititci, 2006).The talking to of the services is capable of being dvided into three sub sectors and these include accommodation, transportation and incoming travel services. The performance of the delivery stage is one that is affected by the various relations between these main industry players. Hence, it can be said here that performance measures would be required to reflect the interdependency features of the industry(Yilmaz and Bititci, 2006).The transportation part of the service is where logistics really come into play and the existance of bad infrastructure would damage the entire service offering.2.3 The Concept of Tourism YieldDwyer and Forsyth, (1997)state here that tourism yield can be said to be the net benefit that accrues to the host country from international visitors and this means that it is the benefits minus the costs of tourism activity. This particular definition does believe the c omplexity of identifying, at the national level, all of the costs and the benefits of tourism, and every one of these has different kinds of patterns of activity and impactAt the firm level, a measure like this is very critically important as it is a measure of survival. In essence,Tisdell (1993)has provided a list of target variables of possible importance to governments when it comes to formulating policy in terms of foreign tourism and these are listed out belowforeign sub earningsnet national economic benefits that are obatined from foreign tourists as being measured by changes that take place within the economic surplusesemployment generationcultural and sociological impact in regards to the host populationconservational or environmental impactpromotion of international understanding and co-operationincome distribution consequences.(Dwyer andForsyth, 1997)2.4 trade for Tourism and Recreational ServicesIt is noted here that the market of tourist and recreational services is co mposed of the followinghospitality servicescatering servicestour operating servicestourism oriented servicesrecreation oriented services(Kordel, 2008)It is these segments of the market where a large number of firms, business entities and alsoincorporated companies are said to operate easily and are able to successfully adopt the concept of logistics. Essentially speaking, the science of logistics is said to combine speculative andpractical issues and each and every one of its theories is capable of being easily implemented as well as confronted with realityfor the purposes of verifying that they are efficient and applicable in real life(Kordel, 2008)2.5 Logistics and Cost Analysis IssuesFor instance, taking into account the hospitality services sector, it is noted that there are some areas where logistics play a vital role and it is noted here that the efficiency as well as the quality of hospitality services is capable of being improved via efficient logistics management of the fo llowinghotel managementquality management development managementmarketing(Kordel, 2008)In looking at the hospitality sector from a very comprehensive point of view, a number of different processes are observed to take place and these include the followingsupply processesservice production processesdistribution processesstorage and warehousing processesinformation transmission processes(Kordel, 2008)2.5.1 Minimalization of CostsThese areas that have been outlined above have to be referred to when it comes to searching for minimalization of costs as well as to locate the most appropriate solutions that are possible for the purposes of gaining a strong, a very competitive and very leading position within the market(Kordel, 2008). All of these processes have to be examined from the view point of costs that they are bringing about and then be classified according to genre and amount. This would permit for the reckoning of total and unit logistics cost, and these are noted to be very ess ential factors that impact the competitiveness of companies. Total logistics costs analysis can be described as being the main key to managing the logistics function and this is why it is essential that the management take into consideration all logistics cost(Kordel, 2008)With the hotel industry, for instance, the total amount of logistics cost is said to include the followingcost of supply activitiescost of informationcost of operationcost of marketingcost of distributioncost of supererogatory servicescost of insurancecost of transport activitiescost of personnelother financial costs(Kordel, 2008)2.5.2 Utilization of Costs Analysis to Improve Logistics PracticesIn essence, the issue of costs is said to be an essential problem and due to the fact that its role in todays economy can be said to continue to grow, they have to be brought up to everyones attention, they have to be properly classified, diagnosed, analyzed and then utilized for the purposes of decision making process. Ho wever, most of the companies can be said to be fitted with basic financial and accounting systems and it is noted here that these do not register the logistics costs and it makes it hard to which makes it difficult to diagnose andanalyze them(Kordel, 2008).The processes noted above have to eb examined from the point of view of costs. The utlization of cost analysis is noted to be carried out accroding to these above specifications and could help when it comes to calculating all of the logistics cost concerning the particular firm in the tourism industry and it will also indicate the kind of components that are able to generate the most costs and hence are required to be minimized. It is appreciated here that companies can easily enhance their market competitiveness by reducing their logistics costs abnd this eventually results in ominous the total costs of goods and services(Kordel, 2008).Because it might be hard to make a determination of the individual component oflogistics costs that have to be reduced, companies need to make attempts to integrate thelogistics system as opposed to lowering total logistics costs. This kind of solution can be said to be very gumshoe especially that wrong diagnosis of individual costs may lead to an increase of totallogistics costs. Hence, it is essential to remember that in tourism and hospitality business, the effective cost reduction as well as the ability to manage the total logistics costs in the right way can be said to be very helpful when it comes to building a strong position in the market(Kordel, 2008).In essence, keeping track of all logistics costs that are said to be borne by companies from tourist and recreation sector could be easier if only these companies are equipped with additional software that are dedicated towards logistics costs registration and these companies are able to carry out regular research by themselves concerning their very own initial costs.m In general terms, for the hospitality sector to be capable of operating properly and without any sort of objections, there are some issues that have to be taken into account and these are as followsModern logistics solutions have to be constantly updated and implementedThere needs to be an analysis of supply chain costsThere has to be a much wider spectrum of dogmatic system that has to be implementedEssential decisions that are made have to be consulted with professionals.(Kordel, 2008)For the purposes of having a better understand of the concept that is try to be presented here, the following matters need attentionServices that are provided by these firms need to meet certain quality standards.Customer are to be considered as being merchandise and all the costs that are borne need to be classified as being according to the logistics processes.Realization costs related to controlling systems that are orne in logistics processes need to be implementedThere has to be accurate and prompt decisions that need to be made in relation to logisticsprocesses being executed.(Kordel, 2008)2.6 The Role of randomness Technology in the Tourism Industry and its Impact of LogisticsThe information technologies are said to play a very significant role within the tourism industry and it is appreicated here that the impacts of the mesh(Wynee et al., 2001) and (Dambro and Wilson, 2004)and the computer reservation systems(Duliba and Kauffman, 2001) and (Alamdari, 2002)within the distribution value channel of tourism are subjects of thorough discussion. Information technologies do permit the suppliers, like the airlines and hotels, to be capable of monitoring, managing and controling their capacity via communicating with the intermediaries together with the end consumers. For instance, it is noted here that authorized tour operators are able to access a dedicated part of a hotel companys intranet in order to be able to view room rates and the availability of these rooms for their customers. such(prenominal) kind of transparen cy as well as interactivity makes it possible to increases the efficiency as well as the productivity of all of the value chain (Buhalis, 2003).It can be theorized here that IT does enhance logistics very well and it enhanced speed, efficiency and dependability within the entire tourism industry.3.0 MethodologyIn this chapter, the methodology of the research will be outlined very comprehensively. This means that there will be an refinement of the various methodological tools that will be used in this research for the purposes of collecting data. These are the tools that will be used to gather information that will then be subjected to analysis and for conclusions to be drawn. For this research, there would be the use of primary and secondary research tools that will be utilized in conjunction with each other. The use of both these tools will ensure that quality data will be obtained for the puposes of the research. The research design and the notional framework for the research wi ll also be outlined in this chapter.3.1 Methodological Tools UtlizedAs noted frontly, the methodological tools that will be utlized here will comprise of a combination of primary and secondary research tools. Below will be an identification and description of the types of tools that are to be used.3.1.1 Primary Research ToolsPrimary research does essentially involves the collection of data concerning a given subject now from the real world. Here, there will be a description of what primary research is, the ethics that are involved with primary research and different types of research that can be done(Driscoll and Brizee, 2010).In essence, primary research is any sort of research that can be done through the use of surveys and interviews. A researcher that is very talented will be one that will be able to use both primary and secondary research sources and to be able to integrate them in a very cohesive fashion. The ability to perform primary research can be said to be a useful ski ll as it is able to acquire information that can supplement ones research in secondary sources(Purdue.Edu -Primary Research, 2010).It is appreicated here that the primary data that has been hive away via the methods that have been described above are generally qualitative in nature or in some cases, quantitative(TVU.AC.UK -Primar Research Methodologies, 2010).For this research, the types of primary research that will be carried out will be as follows1. Interviews2. Questionnaires3.1.2 Primary Research Tool 1 InterviewsInterviews can be described as being one-on-one or small group question and answer sessions that will be carried out by the researcher and the interviewees. These interviews will be abel to provide a great amount of information from a few persons and they are essential when it comes to getting expert or knowledgeable opinion in relation to a particular subject, like logistics in the Malaysian tourism industry(Purdue.Edu -Primary Research, 2010) and (Driscoll and Briz ee, 2010).The advantages of interviews are as follows able-bodied to get accurate information.High response rate.Able to be completed immediatelyAbility for interviewer to help if they is problemsAbility to investigate motives and feelings.Ability to use recording equipment(TVU.AC.UK -Primar Research Methodologies, 2010)In essence, a total of 5 interviews will be carried out with managers from firms within the tourism industry in Malaysia. The researcher aims to get a wealth of information from these managers about their thoughts and perspectives about the performance of the firms in the tourism industry in Malaysia, the issues that are reducing its performance and the strategies that can be used to improve its performance. These interviews will be vital towards the satisfying of the research objectives.3.1.3 Primary Research Tool 2- QuestionnaireQuestionnaires will be the next kind of primary research source that will be utilized here and in this questionnaire can be described as a type of questioning that is far more rigid as opposed to interviews and it also tends to involve much larger groups of people. In essence, these surveys are likely to provide a limited amount of information from a very large group of persons but they are very useful when it comes to having an understanding about what a larger population thinks about the issue concerned(Purdue.Edu -Primary Research, 2010) and (Driscoll and Brizee, 2010).The main advantages of using questionnaires are as followsAble to be used in its own rightAble to be posted, e-mailed or faxed and this increases speed and saves timeAble to cover a large number of personsVery wide geographic coverage.InexpensiveRespondent has the chance to consider responses.There is anonymity of respondent.Absence of interviewer bias(TVU.AC.UK -Primar Research Methodologies, 2010)A total of cx questionnaires will be distributed to members of the target group and these essentiall comprise of persons from firms within the tourism in dustry in Malaysia. The researcher proposes to collect a large amount of information from this target group in order to determine the issues facing the tourism industry, the practices of these firms, what they are doing to improve themselves and the strategies that they can adopt in order to improve their practices for the benefit of their firm as well as the industry.3.1.4 Secondary Research ToolsSecondary research methods are research methods that are used to collect information from sources that have already been researched on before. Secondary research would involve the processing of data that has already been collected by researcher previously and it makes reference to the consultation of previous studies as well as findings and these include reports, press articles as well as previous market research projects so as to be able to reach a conclusion.A secondary research method would be premised on information that has been collected from studies previously performed and hence it is a reseaerch method that is not very expensive in contrast to primary research because it does not require new research methods. The main disadvantage of this research type is that the information that has been collected might be old and obsolete and this might mean that the results of analysis could be inaccurate(Business Teacher -Primary-Secondary Market Research, 2010).There are a number of secondary research sources that can be used to collect information and the ones that will be utlized for this research invovle the following belowPublished texts concerning theoretical work and aslo secondary analyses that have been carried out by experts and reportsVarious media like the internet, television and radio that act as sources of information(Secondary Research Methods, 2010)Below would be the main advantages of secondary reseaerchInexpensive and highly accessibleOnly method of examining large-scale trendsAbilit to gather a large amount of date especially from the internet(Second ary Research Methods, 2010)3.2 Research DesignIn relation to to reseach design for this project, this relates to the decision making selections that are rational and here there will be an elaboration of the type of speculate that will be carried out, the level of control and other issues related to the project. This research typically involves making a research of the logistics practices and conditions in the Malaysia tourism industry and what improvements that need to be made to enhance the logistics so as to bring positive enhancements to the industry.Concerning the kind of study invovled, this will be an exploratory study as they has been very little research that has been carried out on the logistics of the Malaysian tourism industry and the approaches that have been taken by the Malaysian government to improve it. The level of interference by the researcher was kept minimal so as to ensure that it does not have a bad impact on the research and that the completion of the projec t is not delayed.Practically, there are a number of sampling techniques that can be used for a research like this and these are discussed now. The first of these is cluster sampling and this is the kind of sampling that can be used where the larger population has been divided into much smaller clusters and they are selected randomly for the study. The next type of sampling is systematic sampling and this is a technique whereby the researcher is able to sele

Analysis of Compound 109 using 13C NMR Spectra

Analysis of Compound 109 using 13C NMR SpectraThe 13C NMR spectrum of compound 109-114 is re puzzleed in Plate 40-45. morphological elucidation of 109 by 13C NMR spectrum has been described and it was confirmed from the two dimensional NMR reports of 109. Assignments for the other compounds 109-114 made by comparing with compound 109. put over 33 lists the chemical shift values of 109. A collection of signals resonated in the aliphatic orbit at 20.85, 26.60 and 27.98 ppm of the three signals in the aliphatic region, signals at 20.85, 26.60 and 27.98 ppm are charge to C-7, C-6 and C-8, respectively. The C-5 signal is merged with solvent signal. In addition to this, the benzylic degree Celsius signals C-2 and C-4 were resonated at 64.53 and 62.52 ppm respectively, whereas the bridgehead carbon C-1 was appeared at 45.69 ppm. Moreover, a collection of signals appeared in the region 102.69-131.40 ppm, which are unambiguously assigned to aryl carbon. A part from the assigned signals, two signals resonated in the downfield at 142.56 and 142.72 ppm is assigned to ipso carbons. Another four unassigned signals resonated in the down field region at 159.55 to 166.27 ppm and these signals belong to C=0, C=N, C-OH carbons respectively.1H-13C COSY spectraPlate 46 and 47 represents the 1H-13C COSY spectrum of 105 and the correlations showed in Table 34. HMBC (Plate 40) and HSQC (Plate 41) correlations have been used to assign the benzylic carbons, ipso carbons of aryl group, and methylene carbons (C-6, C-7, and C-8). The benzylic protons observed at 4.30 (H-2a) and 4.25 ppm (H-4a) showed cross peak with 64.33 (C-2) and 62.52 ppm (C-4), which whitethorn be due to the C-2 and C-4 carbons of the piperidone heterocyclic of the ABN system. The bridgehead methine proton signals at 2.50 (H-1e) and 2.98 (H-5e) ppm was correlated with the carbon signals at 45.69 ppm (C-1) and 39.57 ppm (C-5). This indicates that the signals appeared at 45.69 and 39.57 ppm is unambigously assigned to C-1 and C-5 carbons. Cross peak with the protons resonated at 2.77 (H-7a) and 1.27 (H-7e) ppm was correlated with the carbon signal at 20.85 ppm and this confirms the signal at 20.85 ppm was solely specific to C-7 carbon.H-6a and H-6e protons appeared at 1.45 and 1.60 ppm showed cross peak with 26.60 ppm (C-6 carbon), which confirms that the signal at 26.60 ppm was due to C-6 carbon and the carbon signal at 20.85 ppm was attributed to the similar C-7 carbon. Similarly, the H-8e (1.63 ppm) and H-8a (1.55 pm) protons was correlated with the carbon signal at 27.98 ppm (C-8), which suppors that the signal at 27.98 ppm was ascribed to the cyclohexane ring carbon C-8.Analysis of spectra of 109-1141H and 13C NMR spectral analysis of other compounds such as N-(2,4-bis(4-chlorophenyl)-3-azabicyclo3.3.1nonan-9-ylidene)-2,4-dihydro-xybenzohydrazide101, N-(2,4-bis(4-fluorophenyl)-3-azabi-cyclo-3.3.1nonan-9-ylidene)-2,4-dihydroxybenzohydrazide 102, N-(2,4-bi-s(4-bromophenyl)-3-azabicyclo3.3 .1nonan-9-ylidene)-2,4-dihydroxy-benzohydrazide 103, N-(2,4-dip-tolyl-3-azabicyclo3.3.1 nonan-9-ylidene)-2,4-dihydroxybenzohydrazide 104, N-(2,4-bis(2-chloro-phenyl)-3-azabicyclo3.3.1nonan-9-ylidene)-2,4-dihydroxy-benzohy-drazide 105 was canvas in a similar way of 109. The chemical shift and splitting patterns observed using 1H and 13C NMR assignments for other compounds is presented in Tables 35 and 36 and their corresponding spectra are given in Plates 33-37 41-45, respectively. Tables 37-42 show the brief description of analytical and spectral data of compounds 109-114. Taken together, all the above observations substantiate the proposed structure and twin-chair (CC) residency of 2r,4c-diaryl-3-azabicyclo 3.3.1 nonan-9-one-4-methyl-1,2,3-thiadazole-5-carbonylic hydrazones 102-108.Biological studyFree composition scavenging activityIntensity of the take over radical scavenging potential strongly depends upon its chemical structure. Several studies have demonstrated that the f ree radical scavenging effects is noticeably influenced by the number and position of hydroxyl radical groups on the D ring and by the extent of conjugation between the D ring amide carbonyl group 1-4. The dihydroxy structure in the D ring confers high stability to the hydrazones phenoxyl radical via hydrogen nonplusing or by negatron delocalization. The amide carbonyl group double bond (Conjugation with the amide oxo group) determines the coplanarity of the phenyl ring and participates in radical stabilization via electron delocalization over all ring system 4. Initial studies on analysis of free radical scavenging potential of diaryl 3-azabicyclononanones revealed a concentration dependent weak anti-radical activity resulting from reduction of DPPH, ABTS+, O, OH, and nitric oxide radicals to their non-radical forms. In order to operate the dihydroxy structure in the D ring and the amide carbonyl group double bond (Conjugation with the amide oxo group) into diaryl 3-azabicyclono nanones to enhance the free radical potential (figure 14), We therefore synthesized N-(2,4-diaryl-3-azabicyclo3.3.1nonan-9-ylidene)-2,4-dihydroxybenzohydrazide (109-114) by the reaction of 95,96,98-101 with 2,4-dihydroxybenzoic acid hydrazide (94) in the presence of acetic acid.All the tested compounds showed a concentration dependent anti-radical activity against heterogeneous free radicals. IC50 values for the free radical scavenging effects of ascorbic acid and various synthetic compounds (109-114) are shown in Table 43.This may be due to the hydrogen pinch donation mechanism and the electron donation mechanism. In the hydrogen atom transfer mechanism, hydroxyl groups donate hydrogen to a radical stabilizing it and giving rise to a relatively stable hydrazones phenoxyl radical. Figure 15 illustrates the probable mechanism of hydrogen atom donating ability of compounds 109-114.The electron donation mechanism involves through the strong hydrogen bond of -OH mediety with the ox ygen atom of amide carbonyl group that may prevent efficient deprotonation and enhance their radical scavenging action by means of hydrogen atom donation. Figure 16 illustrates the probable mechanism of free radical scavenging effects of compounds 109-114 through electron donating mechanism. anatomical structure A is the parent neutral molecule of compounds 109-114. Structure B is the initial radical ions and structure C is its more stable tautomeric form. The tautomeric form C of the radical ions results from the initial radical ions B and proton transfer from C-2 -OH to carbonyl groups.We found required structural features to scavenge free radical in our tested compounds (109-144). However, we have noticed a diverse range of effects against various free radicals. This may be due the different substitution at the C-2 and C-6 positions of the azabicyclononan-9-one moiety. Compound 8 devoid of any substituents at the para position of the phenyl groups at the C-2 and C-6 positions of the azabicyclononan-9-one moiety and phenyl rings with electron-donor methyl groups at the para position of compounds 113 showed excellent free radical scavenging effects compared to standard antioxidant ascorbic acid, a known antioxidant used as a positive control. This may be due to incorporation of methyl groups at para position phenyl ring. Several studies have demonstrated that organic molecules incorporating a methyl groups can act as free radical trapping agents and are capable of opposing oxidative challenges 5,6. Compounds possessing electron-withdrawing chloro (110/114), bromo (111), and fluoro (112), substitutions at the para position of the piperidine moiety showed admirable in vitro free radical scavenging effects against various free radicals. This admirable or less free radical scavenging effects of compounds with bromo, choloro and fluoro substitutions may be due to the electron-withdrawing inductive effect of halogens. The results obtained in the present study are in line with other findings 7,8. Taken together, the current research suggests that azabicyclononane ring ensuring hydroxyl groups on the D ring and by the extent of conjugation between the D ring amide carbonyl group with strong free scavenging effects (111) may conceivably contribute to its protective effects against free radical-induced oxidative stress and carcinogenesis.Antibacterial and antifungal activitySynthesized compounds 109-114 were examined for their antibacterial and antifungal potencies. In vitro studies by forked serial dilution method was adopted. Streptomycin/ streptomycin/ fluconazole were used as a positive control. Table 44 shows the MICs of test compounds 109-114. Analysis of in vitro antimicrobial effects of all the N-(2r,4c-diaryl-3-azabicyclo3.3.1nonan-9-ylidene)-2,4-dihydroxybenzohydrazide 109-114 revealed a diverse range of (1.56-200 g/mL) against the various bacterias and fungus. The compounds deprived of any substituents at the aryl rings in 109 hinder the growth of all bacteria and fungus at a MIC value of 100-200 g/mL. However, compounds 110, 111 and 112 possessing para halo (electron withdrawing substitutents chloro, fluoro and bromo) substituted aryl groups in azabicyclononane moiety accounts for the enhanced inhibitory effects against B. subtilis, K. pneumonia, P. aeruginosa, S. aureus, A. flavus, A. Niger, C. albicans, and Candida6 at MIC values of 1.56-25 g/mL when compared to the standard antibiotic streptomycin/ fluconazole.Several studies have also documented that electron-withdrawing groups (fluoro, bromo and chloro) substituted azabicyclononan-9-one derivatives exhibited outstanding antibacterial and antifungal activities 9,10. Compound 114 with ortho chloro substituent in the phenyl moiety displays goodish antibacterial activity against all pathogens. separate compounds displayed reduced inhibitory effects against various bacterial strains compared to the standard streptomycin/ fluconazole. The results of the prese nt study demonstrates that electron withdrawing groups at the para position of the aromatic ring in azabicyclononan-9-one moiety exert superior inhibitory effect against various tested microbes compared to the other test compounds and standard drug. The SARs based on IC50 values (table 44) showed that variations in substitution of the aryl groups at C-2 and C-4 position of the azabicyclononane ring may have significant impact on the anti-microbial activity against various microbes.ConclusionThe chemical condensation of variously substituted diaryl 3-azabicyclononan-9-ones with 2,4-dihydroxybenzoic acid hydrazide in the presence of acetic acid provide corresponding hydrazones 109-114 with increased antioxidant potential and anti-microbial effects. Although various hydrazones exerted the free radical scavenging effets in a good dose-dependent manner, compound 109 and 113 were more active in scavenging free radicals than their parent hydrazones and ascorbic acid. In addition, the resu lts of the antimicrobial activities of hydrazones revealed that compounds 110, 111 and 112 possessing para halo (electron withdrawing substitutents chloro, fluoro and bromo) display promising activities against all tested microorganisms. The results of the present study provide a further insight into the structural requirements to develop potential new antioxidants and anti-microbial agents.

the deathmetal bands of today :: essays research papers

Official deathmetal band of 2001 many of them are saanist but hundreds are good ol christians.Abominant secure ZeroAceldamaAcerbusAcheronAcrimonyAgent SteelAmon AmarthAmorphisAnal BlastAnal CuntAnasarcaAncientAncientCeremonyAngel CorpseAriusAutopsy TormentAutumnLeavesAvulsedBal-Sagoth threatBastardwordBeheadedBenevolenceBleeding DisplayBlood CovenBloodgasmBloody SignBloodvomitBolt ThrowerBorknagarBrodequinBroken HopeBrutal NoiseButchery adenoidalCannibal CorpseCarcariassCarnal GriefCastrumCatastrophicCentinexChildren Of BodomCiboriumCineraryCiribusCoffin TextsCoprofagoCorpsevomitCrack UpCremationCrematoriumCrest ofDarknessCrimson ThornCryptopsyDamien ThorneDark old ageDark DiscipleDeadenDead JesusDeamonDecapitatedDecay Of SalvationDeeds of FleshDeicideDefleshedDehumanizedDemionDeprecatedDerangedDescendentDevourment unhallowedDiabolic IntentDiabolousDimmu BorgirDismembered FetusDisgorgeDivine EmpireDivine RaptureDying FetusDwelling MadnessE.C.T.EnforsakenEngraveEnshroudEpicedium star k(a) crying of SorrowEulogyEvil IncarnateExhumatorExposing InnardsFamineFates WarningFleshcraveFleshgrindGallery of DarknessGates of IshtarGod DethronedGorgasmGorlockHadez HordeHateHate EternalHate PlowHatescarHateworkHavohejEnorhtedHellwitchImpaledImmolationImmortal DominionIncantationInfamyInfernal MajestyInfernal TormentInfest And CorruptInfestumInflamesInfusionInhuman annoyanceInsanityInternal BleedingJudas PriestKabakKataklysmKrabathorKrisiunLangsuirLehavothLeukorrheaLividityLockupMaladictionMalamorMaleficentMalevolent CreationMalignancyMeatshitsMeltdownMorbid AngelMonstrosity mortician<?A>MortuorioNecrophagiaNeurosisNew PlagueNileNightwishNinth LevelNoctuaryNun SlaughterObeliskObituaryObscurityOf Trees And OrchidsOratoriumOriginOrphanage stress InventionPessimistPostmortemProphecyPutrilagePurgatoriaPurge CannisterRancorRegurgitationRequiemRiseRiseRudraSadistic IntentSanctorumScytheSepsismSevenday CurseSetherial nauseaSirrahSinergySinisterSix Feet UnderSkinlessSlaughter Of SoulsSlayerSolstice of SufferingSplattered CadaverStratovariusSuffocationTchildresThanatosThe InsomniaThe KovenantTherionThorazineThy SerpentTiburonTonTrokarTwin commonnessUnnatural EndUnsanctifiedVictims of Internal DecayVillainthrophyVociferation EthernityVulpeculaWarmenWithinWormedVaderVehemenceViiarcanoVileViolenciaViral LoadVirusVisceral Bleeding dissectVomit RemnantsBut there are un official deathmetal abnds as well here are some of themBrujeriaCannibal CorpseCannibal Corpse tissue of Razors(COB)Children of bodomChildren of BodomDeathDimmu BorgirHate EternalMorbid AngelNightwishSepsismSinister SlaytanicTherionVenomDeathmetal is a low sounding violent assult on all your cense and it is drive evermore popular in the subculters of todays y stunnedh. bands like cannibal corpse and slayer with some what satanic lyrics and punching chords todays youth have no choice but to become the children of the new disease.here is an qutobioThe StoryBack in Buffalo,NY in 1989 the breaking u p of two bands, Tirant Sin and Beyond Death, resulted inthe creation of a freak called "Cannibal Corpse". The group recorded a demonstration in Niagara Falls, NYentitled "Cannibal Corpse", not "Suffocation" like many of you think. The demo caught the eye of Metal Blade Records and the band was signed right away. The birth of"Eaten Back To Life" was the commencement exercise step to being the GODS of death metal. Check out thediscography section for a complete listing of albums and song titles. There have been several changes in the line-up throughout the bandss history, First the departure ofBob Rusay. Listen to the first album & you will understand why. Without Jack Owen, theguitar-playing on the album would sound like mud. The acquisition of fellow Buffalonian Rob Barrett,who had also played in Dark Deception, Solstice and Malevolent Creation was a welcomed change.Rob left Cannibal Corpse in late 97 to persue other areas. Next came the departu re of Chris Barnes who later create his own band, Six Feet Under. Thisoccured during the recording of "Vile" which was, at the time, tentatively entitled "Created to Kill".Thats where George "Corpsegrinder" Fisher came into play. He has been a change for the better andhas done a great job in filling the shoes of a great singer for his time.

The Black Cat - Symbolism Essay -- essays research papers

Symbolism in Edgar Allan Poes "The Black Cat" &9In Edgar Allan Poes "The Black Cat," symbolism is used to show the narrators capacity for violence, madness, and guilt. "The Black Cat," written by Edgar Allan Poe serves as a monitoring device for all of us. The Capacity for violence and horror lies within each ofus, no matter how docile and humane our disposition might appear. In this story, the narrator portrays a man who is fond of animals, had a tender heart, and is happily married. Within several years of his marriage, his general temperament and character make a radical diversity for the worse. He grows moodier, more irritable, and more inconsiderate of the feelings of others. This change for the worse caused by alcohol, ends in the narrators waiting on death row for the put to death of his wife. The symbolism of the first black cat(Pluto), the second black cat, and the white spot illustrate the narrators expanding capacity for evil and perverseness .&9The more or less important symbol of the story is the first black cat. The first black cat is symbolic of the narrators evil heart and there are many ways one can prove this. Black cat one started out in the story as the narrators best-loved pet and playmate named Pluto,which is the name of the God of the Underworld. And one night, after returning home much intoxicated the narrators love for the pet be to fade away. That night in which the narrator is...